Volcanic rocks could store captured CO2, study finds

Rocks formed by ancient volcanoes found across the UK could safely store millions of tonnes of CO2 by turning it into stone, according to new research.

Waterstein Head from Neist Point, Isle of Skye, Scotland.
Waterstein Head from Neist Point, Isle of Skye, Scotland. Credit- Professor Mark Wilkinson, University of Edinburgh.

Scientists have identified eight underground volcanic formations that could store over 3,000 million tonnes of industrial COwaste – equivalent to around 45 years worth of the country’s industrial emissions.

The study, led by researchers from the University of Edinburgh, analysed the geology, chemistry and volume of reactive rocks from around the UK, including basalts in Country Antrim in Northern Ireland, the Isle of Skye in Scotland and in the Lake District, England.

Carbon mineralisation

Rocks in these areas are rich in calcium and magnesium, which readily binds with CO2 to form a solid mineral in a process known as carbon mineralisation. 

This works by dissolving captured CO2 in water and injecting the carbonated water into volcanic rocks deep underground. Mineralisation occurs in the spaces and cracks that are naturally present in the rocks, turning the carbonated water into stone.

The research team calculated how much CO2 each rock group could hold by combining the surface area and thickness of the rocks with details of their chemistry.

Pilot projects

Mid-range estimates found that the Antrim Lava Group in Northern Ireland offered the largest storage potential of 1,400 million tonnes of CO2. The Borrowdale Volcanic Group in England was estimated to offer 700 million tonnes, while the Skye Lava Group could store around 600 million tonnes. 

Pilot projects in Iceland and the USA have already shown that CO2 mineralises rapidly and securely. Larger scale projects are ongoing to measure the amount that can be stored by this method.

Storage potential

Safe, permanent storage of CO2 will be required to limit g­lobal warming to between 1.5 and 2 °C above pre-industrial levels, with mineralisation providing a storage solution for the UK, researchers say.

The study was published in Earth Science, Systems and Society, issued by the Geological Society of London, and was funded by the National Environment Research Council (NERC).

Sustainability pledge

The University of Edinburgh is committed to creating a more sustainable world through its world-leading research, teaching, partnerships and innovations.

Recognised as one of the world's top universities for environmental and social impact, tackling the climate and environmental emergencies are a key part of the University's mission to become carbon neutral by 2040. 

By showing where the UK’s most reactive volcanic rocks are and how much CO₂ they could lock away, we highlight a practical and permanent way to mitigate unavoidable industrial emissions, adding to the UK’s arsenal of decarbonisation options.

To cut CO2 emissions at scale, we urgently need carbon storage. CO2 mineralisation offers the UK more room to store CO2, adding to the huge resource offered by the rocks beneath the North Sea.

“Our next steps are to assess effective porosity and rock reactivity in detail. This will tell us how efficiently each formation can mineralise CO2 in practice.

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