The findings indicate the material, which was until now thought near-impossible to make, can act as a highly effective semiconductor – a key component of modern electrical devices.
Using the new semiconductor in electronics such as computer processors or medical imaging devices could help them run more efficiently, the team says.
New semiconductor
The material – made by combining the chemical elements germanium and tin – can absorb and emit light more effectively than commonly used semiconductors made of silicon.
It works by facilitating the conversion of light into electrical energy, and vice-versa, which is key to the operation of so-called optoelectronic devices, the team says.
While previous research had suggested that the germanium-tin alloy could in theory act as an effective semiconductor for converting light to and from electrical energy, producing it had proven very challenging.
This is partly because the elements do not chemically react with each other under normal conditions.
Extreme conditions
Now, a team led by Edinburgh researchers has created not just a single material, but an entirely new class of semiconductors made of germanium-tin.
The approach involves heating mixtures of germanium and tin to more than 1200 degrees Celsius, while applying pressures of up to 10 gigapascals – around 100 times greater than the pressure at the bottom of the Mariana Trench, the deepest point in the ocean.
The process produces stable germanium-tin alloys at room temperature and pressure that could function as effective semiconductors, the team says.
The research, published in the Journal of the American Chemical Society, was supported by the European Commission. An open access version of the paper is available here: https://www.research.ed.ac.uk/en/publications/high-pressure-and-compositionally-directed-route-to-a-hexagonal-g/.
The work involved researchers from the University’s Schools of Engineering and Geosciences, the GFZ Helmholtz Centre for Geosciences, the University of Lille, Grenoble Alpes University, the University of Bayreuth and the European Synchrotron facility.